Isotherm and Kinetic Studies of Flouride Removal on Activated Carbon obtained from Coconut Shell
Abstract
Activated carbon was prepared using coconut shell according to standard method. Langmuir and Freundlich isotherms as well as pseudo-first order and pseudo-second order were studied. The Freundlich isotherm confirmed suitable match with the experimental information with high correlation coefficient. The kinetic parameters confirmed that the maximum favourable order for the adsorption technique is the pseudo-second order kinetic. Outcomes showed that activated carbon prepared from coconut shell was very powerful in the defluoridation of water with approximately 73.1 % fluoride removal at a reaction time of fifty minutes, temperature of 30oC, and adsorbent dose of 1.5 g.References
Reference
Lal Sunder, Adarsh, Pankaj,. Text book of Community Medicine Preventive and
Social Medicine. Fifth Edition, CBS publisher & distributors Pvt Ltd, New Delhi, 2017.
Jha SK, Singh RK, Damodaran T, Mishra VK, Sharma DK, Rai D. Fluoride in groundwater: toxicological exposure and remedies. J Toxicol Environ Health B Crit Rev. 16 2013 52-66.
Raghavan R, Bipin N, Abraham A. Prevalence of dental fluorosis and fluoride content of drinking water in rural areas of Malappuram district, Kerala. Int J Med Sci Public Health, 3 2014, 27-30.
WHO. The World Oral Health Report; Poul Erik Peterson. Genera: World Health
Organization, 2003.
Emmanuel M., Danbature W. L.,Shehu Z.., Solomon P. K. Equilibrium, Isotherm and Kinetic Studies of Flouride Adsorption on Activated Rice Husk Ash, Innovat International Journal of Medical & Pharmaceutical Sciences, 2018, 3, 17-21.
Danbature W. L., Shehu Z.., Yirankinyuki F. F., and Solomon P.K. Temperature effect and thermodynamic adsorption of fluoride on activated coconut shell carbon, activated montmorillonite clay and rice husk. International Journal of Advanced Research in Chemical Science: 2017, 4, 21 – 27. DOI: http://dx.doi.org/10.2043/2349-0403.0409003
Ravikumar A., and Nazeeb- Khan S. M. Mitigation of Fluoride from Groundwater by Natural Clay as an Adsorbent, Iranica Journal of Energy and Environment, 2015 6, 316-322.
Kofa G. P., V. Gomdje V. H., Telegang C., and S. Ndi K. Removal of Fluoride from Water by Adsorption onto Fired Clay Pots: Kinetics and Equilibrium Studies, Journal of Applied Chemistry, 2017, 1- 7, https://doi.org/10.1155/2017/6254683
Wilson Lamayi D, Shehu Z, Solomon Kwarson P. .Aqueous Phase Removal of Fluoride as Fluorosis agent Using Montmorillonite Clay as a Natural Nanoadsorbent. Nanochem Res, 2018 3, 219-226. DOI: 10.22036/ncr.2018.02.012
Zhang Y., Wang D., Liu B.., Xiang Gao X., Xu W., Liang P., Xu Y. Adsorption of Fluoride from Aqueous Solution Using Low-Cost Bentonite/Chitosan Beads, American Journal of Analytical Chemistry, 2013, 4, 48-53, http://dx.doi.org/10.4236/ajac.2013.47A007
Shehu Z., Danbature W. L., Ayuba L. and Bulama B. M. Adsorption and Optimization Studies of Congo Red from Solution Using Montmorillonite-Silica Nanocomposite, Current Journal of Applied Science and Technology, 2018, 30, 1-10
Masindi V., Gitari W. M. and Ngulube T. Defluoridation of drinking water using Al3+-modified bentonite clay: optimization of fluoride adsorption conditions, Toxicological & Environmental Chemistry, 2014, 1-13, DOI:10.1080/02772248.2014.977289
Islamuddin R.,Gautam K., Shaista F. Removal of Fluoride From Drinking Water By Coconut Husk As Natural Adsorbent, International Journal Of Engineering Sciences & Research Technology, 2016, 50, 84-846.
Abusu C.O., Muhammad A. K., Schoeneich K., Ibrahim A. A., Dibal H. U. Water Defluoridation Efficiency of Clays From North Central Nigeria: Preliminary Report from Langtang And Environs, The International Journal of Engineering and Science (IJES), 2017, 6, 82-88.
Rajani S. Advances in Application of Natural Clay and Its Composites in Removal of Biological, Organic, and Inorganic Contaminants from Drinking Water, Advances in Materials Science and Engineering, 2011, 1- 17, doi:10.1155/2011/872531
Gogoi P. K. and Ruby B. Flouride Removal From Water by Adsorption on Acid Activated Kaolinite Clay, Indian Journal of Chemical Technology, 2008,15, 500-503.
Abdulhameed A., Mbuvi H.M., Changamu E.O. Removal of Fluoride Ion by Silicon Nitride Powder, Int J Water Wastewater Treat., 2017, 3, 1-7, http://dx.doi.org/10.16966/2381-5299.137
Coetzee P. P., Coetzee L. L., Puka R. and Mubenga S. Characterisation of selected South African clays for defluoridation of natural waters, Water SA, 2003, 29, 331-338.
Malakootian M., Moosazadeh M., Yousefi N., Fatehizadeh A. Fluoride removal from aqueous solution by pumice:case study on Kuhbonan water, African Journal of Environmental Science and Technology, 2011, 5, 299-306.
Karthikeyan G., Anitha P. and Alagumuthu G. Flouride Adsorption Studies of Montmorillonite Clay, Indian Journal of Chemical Technology, 2005, 12, 263-272.
Keshvardoostchokami, M.; Babaei, L.; Zamani, A.A.; Parizanganeh, A.H.; and Piri, F., Synthesized chitosan/ iron oxide nanocomposite and shrimp shell in removal of nickel, cadmium and lead from aqueous solution. Global J. Environ. Sci. Manage., 2017, 3, 267-278.
Sailaja K. B , Bhagawan. D , Himabindu. V , Jyostna C. Removal of fluoride from drinking water by adsorption onto Activated Alumina and activated carbon, Int. Journal of Engineering Research and Applications, 2015, 5, 19-24.
Maarof H.I., Hameed B.H. and Abdul Latif A. Adsorpti,On Equlibrium Of Phenols From Aqueous Solution Using Modified Clay, Jurnlera Kimia Malaysia, 2003, 3, 85-96.
Kiurski J., Adamović S., Oros I, Krstić J., And KovaÄević I. Adsorption Feasibility In The Cr (Total) Ions Removal From Waste Printing Developer, Global NEST Journal, 14 2012, 18-23.
Bhavna A S., Ajay V.S. and Pathik M.S. Sorption Isotherms and Column Separation of Cu(II) And Zn(II) Using Ortho Substituted Benzoic Acid Chelating Resins, Archives of Applied Science Research, 2011 3, 327-341.